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英语翻译Fig.7 presents the H2-TPR profiles of the M-OMS-2

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英语翻译
Fig.7 presents the H2-TPR profiles of the M-OMS-2 catalysts..
Reduction of all the catalysts occurs in a temperature range of 170–350 °C.The peak position,area,and peak types vary among the catalysts (Table 1),indicating different influence of the doping metal on the OMS-2.These peaks between 200 °C and 350 °C can be ascribed to the hydrogen consumption during the formation of Mn2O3,the reduction of Mn2O3 to Mn3O4,and Mn3O4 to MnO [42].From Fig.7,one can readily observe that Cu-OMS-2 catalyst shows the highest reducibility with the largest H2 consumption (12.14 mol/g) and the lowest starting temperature of 170 °C,which might be caused by the reduction of Cu species [24].Furthermore,the Fe-OMS-2 and Cr-OMS-2 catalysts show lower reducibility with the smallest H2 consumption (10.80 and 10.73 mol/g,respectively),and higher starting reduction temperature (272 °C and 275 °C,respectively).The reducibility of the M-OMS-2 catalysts decreases in the following ord er:Cu-OMS-2 > Ni-OMS-2 >Co-OMS-2 > Cr-OMS-2 > Fe-OMS-2.The higher reducibility indicates the higher mobility of the oxygen species in catalysts.Therefore,Cu can significantly improve the oxygen mobility in OMS-2 catalyst compared with the other doping metals.The TPR results correlate fairly well with the catalytic combustion activities and the XPS results.Similar results have been reported for the silver modified OMS-2 catalysts in the CO oxidation reaction[43].Moreover,Hernández et al.[44] also suggested that Cu could improve the reducibility of OMS-2 and enhance the catalytic activity in preferential oxidation of CO.The promotion effect of Cu on the reducibility of OMS-2 could be attributed to the formation of Cu–O–Mn bridge and the hydrogen spillover from Cu atoms to manganese oxides [24,45].Combined with the XPS and H2-TPR results,it can be concluded that the highest catalytic activity of Cu-OMS-2 catalyst can be ascribed to the richer defect-oxide species and the higher reducibility or oxygen mobility.Benzyl alcohol oxidation over OMS-2 catalyst has been proposed to obey the Mars–van-Krevelen (MVK) mechanism [31].
英语翻译Fig.7 presents the H2-TPR profiles of the M-OMS-2
以下翻译房东审查,其中有几个打字的的问题(7ow)位,只是试图理解翻译
3.结果与讨论
3结果与讨论
3.1压降 3.1压降
在文学作品中的压降数据经常被报道的Z因子,这是deBned PPSM ratioof = PPEM,其中PPSM PPEM的压力下降到静态混合器和空管,分别为(首领&Czaskiewicz 1982).的压降数据在文献中,经常报道PPSM = PPEM的比率被定义为Z因子,这里的PPSM PPEM的静态混合器的压降和空气压降的管(首领&Czaskiewicz 1982).这些值吗?根据在同一REEM,空管的雷诺数,这是deBned为REEM = DU 其中,D,管直径,平均7ow速度,和运动粘度,.这些值是根据在同一REEM,即,空的管道雷诺数,它被定义为REEM =都=?在这里,D,U,分别为直径的管子,平均7ow速度的运动粘度.
图2描绘了Z因子对于目前搅拌器的基础上的压力
下降此处测得的数据./>图2描述了混频器的基础上,测得的压降数据Z因子.
层湍流过渡
可能是位于约Re = 150时,相关的保罗和Muschelknautz的(1982年)
层流 - 湍流转捩可以位于约重= 150,这是关系与保罗和Muschelknauts(1982).
这样的观察表明,静态混合器可以启动“早期过渡动荡相比,空管的情况下(2,100-4,000)
这一观察结果表明,ATC的情况下相比也就是说,静态混合器可以引发动荡的早期转换
在相关文献中的一些SK型搅拌机的Z因子的相关性,像格雷斯(1971);陈(1973);威尔金森和CLI?( 1977年);保罗和Muschelknautz(1982)和海伍德,维妮,斯图尔特(1984年),这是基于尊重搅拌机mostof
比超过统一.Z因子在文献中可以一些关于SK型搅拌机的关系,例如:格雷斯(1971年),陈(1973);威尔金森和CLI(1977);保罗和Muschelknautz(1982年)和海伍德,维妮,以及斯图尔特(1984年),其中大部分是基于格式的比率超过1混频器为基础的,为了比较的目的,只有层7ow保罗和Muschelknautz的(1982年)的相关性示出作为图中箭头2的协议/>是令人满意的清酒比较,只有保和Muschelknautz(1982)上的层流关系7ow的箭头所描述于图2.一致性是令人满意的.